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1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Classified as
Hazardous
according to criteria of ASCC1 and
Dangerous Goods
according to the ADG2 Code
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UN NO:
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1993
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D.G. Class:
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3
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Pack. Group:
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III
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HAZCHEM:
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3[Y]
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SUB. RISK:
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None allocated
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SUSDP:
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5
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2. COMPOSITION / INFORMATION ON INGREDIENTS
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Component
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CAS No
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Weight %
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Bitumen
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8052-42-4
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30-60
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Mineral turpentine
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9005-90-7
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30-60
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Pigment and extenders
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*
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0-50
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Additives
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*
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1-10
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* either not classified as hazardous or below relevant concentration cut-offs.
See Section 8, Exposure Controls / Personal Protection
3. HAZARDS IDENTIFICATION
Flammable.
Harmful if swallowed.
Irritating to eyes and skin.
Harmful: may cause lung damage if swallowed.
4. FIRST AID MEASURES
Eyes:
Immediately flush with water for 15 minutes. Get medical attention if irritation develops or persists.
Skin:
Take of all contaminated clothing.
Wash contaminated area with soapy warm water. Get medical attention if irritation develops or persists.
Wash contaminated clothing before reuse.
Inhalation:
Remove to fresh air. Apply resuscitation if victim is not breathing. Give oxygen if breathing is difficult. Get medical attention.
Ingestion:
Consult a doctor immediately. DO NOT induce vomiting. Aspiration into lungs via vomiting can be fatal. Rinse mouth thoroughly. Never give anything by mouth to an unconscious person. Decision to induce vomiting should only be made by a physician.
5. FIRE FIGHTING MEASURES
Flash Point: 52 C closed cup
Auto-ignition Temperature: 300 C mineral turpentine
Lower Explosive Limit: 0.6-1
Upper Explosive Limit: 6.5-7
Suitable Extinguishing Media:
Foam, carbon dioxide, dry chemical. Water is not generally suitable. Water mist can be used to reduce rate of burning and for cooling containers. Do not use water in a jet.
Protective Equipment for Fire Fighting:
Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Fire Fighting Procedures:
Vapours may form explosive mixtures with air. Use water spray to cool exposed containers. Avoid spreading burning liquid with water spray. Stay up-wind and fight fire from a safe distance. Prevent spillage from entering drains or watercourses.
Fire and/or Explosion Hazards:
Vapours are heavier than air and may travel back to source of ignition (electrical equipment, sparks, pilot lights etc.). Containers exposed to heat may explode. Vapours may form explosive mixtures with air.
Decomposition Products:
Decomposes with fire to give off toxic and irritating fumes.
6. ACCIDENTAL RELEASE MEASURES
CAUTION: Flammable liquid.
Isolate hazard area and deny entry to unnecessary or unprotected personnel. Stay upwind and keep out of low areas. Shut off leaks, if possible without personal risks. Eliminate all sources of ignition. Vapours may travel long distances to source of ignition (electrical equipment, sparks, pilot lights etc.). Ensure adequate ventilation. Wear appropriate personal protective equipment including gloves and safety glasses. Do not breathe vapour. Contain spill. Do not allow into drains or waterways.
Small Spills:
Take precautions against static discharge. Use non-sparking tools. Take up with inert absorbent material (e.g. sand, dirt, or vermiculite). DO NOT use sawdust. Fill into marked, sealable containers for disposal. Dispose of empty containers in accordance with federal, state and local laws.
Large Spills:
Notify Emergency Services and advise nature of spill and material hazard. Isolate area. Eliminate all sources of ignition. Vapours may travel long distances to source of ignition (
e
lectrical equipment, sparks, pilot lights etc.). Ensure adequate ventilation.
Additional Advice:
Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained.
7. HANDLING AND STORAGE
Classified as Dangerous Goods - Class 3 Flammable Liquid -
Transport and store in accordance with Dangerous Goods requirements. Store away from combustible materials, excessive heat and sources of ignition. Store away from oxidizing
agents, strong acids and alkalis. All equipment and containers must be earthed to avoid static discharge. Use in a well-ventilated area. Avoid breathing vapour and contact with skin and eyes. Wear gloves, long sleeved shirt, and eye protection. Keep containers tightly closed and store in a cool, well-ventilated area.
Handling -
Avoid inhaling vapour and/or mists. Avoid contact with skin, eyes, and clothing. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical continuity by bonding
and grounding (earthing) all equipment. Handling Temperature: Ambient.
Storage -
Must be stored in a well- ventilated area, away from sunlight, ignition sources and other sources of heat. Keep away from oxidizing agents. The vapour is heavier than air. Beware of accumulation in pits and confined spaces. Storage Temperature: Ambient.
Empty container warning -
Do not reuse empty drums or containers. Do not cut, drill, grind or weld on or near empty containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
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NOHSC |
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TWA
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STEL |
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Component |
(ppm) |
(mg/m3) |
(ppm) |
(mg/m3) |
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Mineral turpentine
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-
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480
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-
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a
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a = not listed
TWA = Time Weighted Average
STEL= Short term Exposure Limit
NOHSC: National Occupational Health and Safety Commission (
Australia)
Respiratory Protection
If vapours and mists occur, a respiratory protection program meeting Australian Standards AS- 1716 and AS-1715 requirements must be followed whenever workplace conditions warrant a respirator's use. None required if airborne concentrations are maintained below the exposure limit listed in "Exposure Limit Information"
Eye Protection
Use chemical splash goggles (Australian Standard AS-1337) or approved equivalent. Eye protection worn must be compatible with respiratory protection system employed. An eye wash station and safety shower should be available in the work area.
Hand Protection
Impermeable gloves as necessary to prevent skin contact. E.g. Nitrile or neoprene gloves.
Engineering Controls (Ventilation)
Use local exhaust ventilation sufficient to maintain exposure levels below exposure limit concentrations. Refer to Australian Standard AS-1668.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Black, viscous
State: Liquid
Odour Characteristic: Hydrocarbon
pH: Not applicable
Viscosity: Not specified
Specific Gravity (Water = 1): 1-1.4
Vapour Density (Air = 1): >1
Vapour Pressure: Not specified
Melting Point Not specified
Boiling Point: Typical 148 - 200 C mineral turpentine
Solubility in Water: Insoluble
Flash Point: 52 C closed cup
10. STABILITY AND REACTIVITY
Considered stable under normal conditions of use and handling.
Hazardous decomposition products:
Oxides of carbon. Decomposition by heat may give off toxic and irritating fumes.
Materials to avoid:
Strong oxidising agents.
Conditions to avoid:
Heat, flame and other sources of ignition.
Hazardous Polymerisation:
Will not occur.
11. TOXICOLOGICAL INFORMATION
The following is supplier data for mineral turpentine.
Ingestion: Aspiration into the lungs when swallowed or vomited may cause
chemical pneumonitis which can be fatal.
Acute Dermal Toxicity: Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Acute Inhalation Toxicity: Expected to be of low toxicity: LC50 greater than near-saturated vapour concentration. / 4 hours, Rat
Skin Irritation: May cause moderate skin irritation. Prolonged/repeated contact
may cause defatting of the skin which can lead to dermatitis.
Eye Irritation: Expected to be mildly irritating to eyes.
Respiratory Irritation: Inhalation of vapours or mists may cause irritation to the
respiratory system.
Sensitisation: Not expected to be a sensitiser.
Repeated Dose Toxicity: Auditory system: prolonged and repeated exposures to high concentrations have resulted in hearing loss in rats. Solvent abuse and noise interaction in the work environment may cause hearing loss. Central nervous system: repeated exposure affects the nervous system.
Mutagenicity: Not expected to be mutagenic.
Carcinogenicity: Limited evidence of carcinogenic effect. (Ethylbenzene)
Reproductive and Developmental Toxicity: Causes foetotoxicity in animals at doses which are maternally toxic. Not expected to impair fertility.
12. ECOLOGICAL INFORMATION
Harmful to aquatic organisms. Keep out of waterways, drains and sewers.
13. DISPOSAL CONSIDERATIONS
Containers hazardous when emptied. Flammable vapour remains in containers until professionally cleaned. Do not cut or drill on or near empty containers. Dispose of empty containers in accordance with federal, state and local laws.
14. TRANSPORT INFORMATION
Classified as Class 3 Dangerous Goods according to the Australian Code For The Transport Of Dangerous Goods By Road And Rail (Seventh Edition). See Section 1.
15. REGULATORY INFORMATION
Workplace Labelling Requirements:
According to Criteria of the Australian Safety and Compensation Council
Risk Phrases
R10 Flammable.
R22 Harmful swallowed.
R36/38 Irritating to eyes and skin.
R65 Harmful: may cause lung damage if swallowed.
Safety Phrases
S16 Keep away from sources of ignition - no smoking.
S23 Do not breathe vapour.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S38 In case of insufficient ventilation, wear suitable respiratory equipment.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S62 If swallowed, do not induce vomiting; seek medical advice immediately and show this container or label
16. OTHER INFORMATION
Australian Safety and Compensation Council
Australian Dangerous Goods Code - Seventh Edition |
